Aqua(iminodiacetato-κ3 O,N,O′)(1,10-phenanthroline-κ2 N,N′)cobalt(II) monohydrate
نویسندگان
چکیده
The imino-diacetate dianion in the title compound, [Co(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O, chelates to the cobalt(II) atom, its N and two O atoms occupying the fac sites of the distorted octa-hedron around the metal atom. The metal atom is also chelated by the N-heterocycle. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through hydrogen bonds, generating a layer motif. The crystal studied was a racemic twin with a 0.62 (2):0.38 (2) domain ratio.
منابع مشابه
Aqua(iminodiacetato-κ3 O,N,O′)(1,10-phenanthroline-κ2 N,N′)zinc(II) sesquihydrate
The imino-diacetate dianion in the title compound, [Zn(C(4)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)]·1.5H(2)O, chelates to the Zn(II) center with its N and two O atoms. The metal atom is also chelated by the N-heterocycle and coordinated by one water molecule, leading to a distorted octahedral environment. The dianion, and coordinated and uncoordinated water mol-ecules inter-act through O-H⋯O hydrogen ...
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In the title complex, {[Zn(C₄O₄)(C₁₂H₈N₂)(H₂O)]·H₂O}(n), the penta-coordinated Zn(II) ion is bound to two N atoms of the 1,10-phenanthroline ligand, two O atoms from two bridging acetyl-enedicarboxyl-ate anions and a water O atom in a distorted trigonal-bipyramidal geometry. The crystal structure is characterized by polymeric zigzag chains running parallel to [2-10] and is stabilized by O-H⋯O h...
متن کاملDi-μ-benzoato-κ3 O,O′:O;κ3 O:O,O′-bis[aqua(nitrato-κO)(1,10-phenanthroline-κ2 N,N′)lead(II)]
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متن کاملAqua(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)(formato-κ2 O,O′)(formato-κO)cobalt(II) monohydrate
The asymmetric unit of the title compound, [Co(HCO(2))(2)(C(14)H(12)N(2))(H(2)O)]·H(2)O, contains a mononuclear complex mol-ecule hydrogen bonded to a lattice water mol-ecule. The Co(II) cation is in a distorted octa-hedral coordination environment defined by the two N atoms of the 2,9-dimethyl-1,10-phenanthroline ligand and four O atoms. Two of these are from a chelating formate anion, one fro...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2008